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Gassing reaction control strategy during charging of Lead-Acid Batteries

Publish Time: 2024-11-20
During the charging process of Lead-Acid Batteries, gassing reaction is a key issue. Effectively controlling the gassing reaction is extremely important for improving the charging efficiency of the battery, extending the battery life and ensuring the safety of use.

First of all, accurate charging voltage control is the basis for controlling the gassing reaction. When Lead-Acid Batteries are charging, when the voltage exceeds a certain value, water begins to electrolyze to produce hydrogen and oxygen, that is, the gassing reaction occurs. Lead-Acid Batteries of different types and specifications have their appropriate charging voltage ranges. For example, the charging voltage of common 12V Lead-Acid Batteries should generally be controlled between 14.4 and 14.8V. By adopting an advanced charging controller, the battery voltage can be monitored in real time, and the charging voltage can be dynamically adjusted according to the charging state of the battery to keep it in the optimal range at all times, avoiding violent gassing reactions caused by excessive voltage. This can not only reduce the generation of gas, but also ensure that the battery is fully charged and improve the charging efficiency.

Secondly, optimizing the charging current is also one of the important strategies. Excessive charging current will cause the internal temperature of the battery to rise and accelerate the gassing reaction. In the early stage of charging, the battery can accept a larger current charge, but as the charging process proceeds, the charging current should be gradually reduced. The use of multi-stage charging methods, such as constant current charging, constant voltage charging and floating charging, can reasonably distribute the charging current according to the battery's state of charge. For example, in the constant current charging stage, the appropriate current value is set according to the battery capacity. When the battery voltage rises to a certain level, it switches to the constant voltage charging stage. At this time, the current gradually decreases, effectively controlling the gassing reaction. It is also beneficial to uniformly charge the battery plates and reduce the occurrence of plate sulfidation and other problems.

Furthermore, the composition and concentration adjustment of the electrolyte have a significant effect on the control of the gassing reaction. Appropriately adding some additives to the electrolyte, such as sodium sulfate, phosphoric acid, etc., can reduce the resistance of the electrolyte and improve the conductivity of the battery, thereby reducing gassing at the same charging voltage. In addition, it is also critical to reasonably control the concentration of the electrolyte. Too high a concentration will reduce the gassing potential and make it more likely to cause a gassing reaction; too low a concentration will affect the capacity and performance of the battery. By regularly testing and adjusting the electrolyte concentration to maintain it at an appropriate level, the gassing reaction can be suppressed to a certain extent.

Finally, the heat dissipation management of the battery cannot be ignored. If the heat generated during the charging process cannot be dissipated in time, the internal temperature of the battery will rise, exacerbating the gassing reaction. For Lead-Acid Batteries, heat dissipation devices such as cooling fans and heat sinks can be used, or the installation layout of the batteries can be optimized to increase the ventilation space between the batteries to ensure that the heat can be quickly dissipated. At the same time, the battery temperature is monitored in real time during the charging process. When the temperature exceeds the set threshold, the charging parameters are adjusted in time, such as reducing the charging current or suspending charging, and charging will continue after the temperature returns to normal, thereby effectively controlling the gassing reaction and ensuring the safe and stable charging of Lead-Acid Batteries.
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